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Hello,

MS Word doesn't allow adding data tables to some chart types (pie, doughnut...). Only specific chart types such as bar or line support data tables.

You can use the legendPos option (https://www.phpdocx.com/api-documentation/word-content/add-chart-Word-document-with-PHP) to set the legend position (bottom, top, left, right...). There's no option in phpdocx to move value positions (MS Word supports this by moving manually the values, but it doesn't include a specific option).
If you want to display the data values in the legend of the doughnut chart, we recommend you add them in the legend values (as part of the text string).

Regards.